Prof. Sawamura / Papers
Prof. Masaya Sawamura (Original papers/Reviews)
Original papers
| 224. Photocatalytic 1,2-Phosphorus-Migrative [3+2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes. Masuda, Y.; Ikeshita, D.; Higashida, K.; Yoshida, M.; Ishida, N.; Murakami, M.; Sawamura, M. J. Am. Chem. Soc. 2023, 145, ASAP. DOI:10.1021/jacs.3c06760 |
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| 223. Gold-Zinc Cooperative Catalysis for Seven-exo-dig Hydrocarboxylation of Internal Alkynes. Sato, M.; Rawat, V. K.; Higashida, K.; Sawamura, M. Chem. Eur. J. 2023, 29 in press. DOI: 10.1002/chem.202301917 |
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| 222. Sheltering Mono-P-Ligated Metal Complexes in Porous Polystyrene Monolith: Effect of Aryl Pendant Stabilizers on Catalytic Durability. Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. Chem. Eur. J. 2023, 29, in press DOI:10.1002/chem.202301847 |
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| 221. Dimetal-Binding Scaffold 2-(Pyridin-2-yl)imidazo[1,5-b]pyridazine-7-ylidene: Synthesis of Trinuclear Heterobimetallic Complexes Involving Gold–Metal Interactions. Kitabayashi, A.; Ono, Y.; Taketsugu, T.; Sawamura, M.; Higashida, K. Chem. Eur. J., 2023, 29, Early View, e202301673 (Hot Paper). DOI:10.1002/chem.202301673 |
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| 220. Sequence-selective Three-component Reactions of Alkyltrifluoroborates with α,β-Unsaturated Carbonyl Compounds and Vinylphosphonium Salts. Yoshida, M.; Sawamura, M.; Masuda, Y. Org. Chem. Front., 2023, 10, 3654-3661. DOI: 10.1039/D3QO00631J |
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| 219. Visible-Light-Induced Aminochlorination of Alkenes. Mejri, E.; Higashida, K.; Kondo,Y.; Nawachi, A.; Morimoto, H.; Ohshima, T.; Sawamura, M.; Shimizu, Y. Org. Lett., 2023, 25, in press. DOI: 10.1021/acs.orglett.3c01645 |
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| 218. Direct α-Trifluoromethylthiolation of Carboxylic Acids Enabled by Boron Catalysis. Sun, K.; Huang, C.-Y.(Dennis) ; Sawamura, M.; Shimizu, Y. Synlett, 2023, 34, in press. DOI:10.1055/a-2071-4465 |
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| 217. Nickel-Catalyzed Defluorophosphonylation of Aryl Fluorides. You, Z.; Masuda, Y.; Iwai, T.; Higashida, K.; Sawamura, M. J. Org. Chem., 2022, 87, 14731-14737. DOI: 10.1021/acs.joc.2c02048
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| 216. Photoinduced Alcoholic α-C–H Bond Anti-Markovnikov Addition to Vinylphosphonium Bromides Followed by Wittig Olefination: Two-step Protocol for α-C–H Allylic Alkylation of Alcohols. Yoshida, M.; Sawamura, M.; Masuda, Y. ChemCatChem., 2022, 14, e202200744(VIP). DOI: 10.1002/cctc.202200744
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| 215. Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes. Rawat, V. K.; Higashida, K.; Sawamura, M. ACS Catal., 2022, 12, 8325-8330. DOI: 10.1021/acscatal.2c01701 |
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| 214. Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of Classical and Nonclassical Hydrogen Bonds. Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.; Higashida, K.; Sawamura, M. Adv. Synth. Catal., 2022, 364, 2333-2339. DOI: 10.1002/adsc.202200327 |
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| 213. Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols. Kitabayashi, A.; Mizushima, S.; Higashida, K.; Yasuda, Y.; Shimizu, Y.; Sawamura, M. Adv. Synth. Catal., 2022, 364,1855-1862. DOI: 10.1002/adsc.202200157 |
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| 212. Visible Light-Induced Reductive Allylation of Aldehydes by Umpolung Approach. Tanaka, I.; Sawamura, M.; Shimizu, Y. Org. Lett., 2022, 24, 520–524. DOI: 10.1021/acs.orglett.1c03927 |
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| 211. Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes. Ueda, Y.; Masuda, Y.; Iwai, T.; Imaeda, K.; Takeuchi, H.; Ueno, K.; Gao, M.; Hasegawa, J.; Sawamura, M. J. Am. Chem. Soc., 2022, 144, 2218–2224. DOI: 10.1021/jacs.1c11526 |
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| 210. Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y. Synlett, 2022,33, 288-292. DOI: 10.1055/a-1673-9236 |
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| 209. Visible-Light-Driven α-Allylation of Carboxylic Acids Sun, K.; Ueno, M.; Imaeda, K.; Ueno, K.; Sawamura, M.; Shimizu, Y. ACS Catal., 2021,11, 9722-9728. DOI: 10.1021/acscatal.1c02558 |
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| 208. Access to Indole-Fused Benzannulated Medium-Sized Rings through Gold(I)-Catalyzed Cascade Cyclization of Azido-Alkynes Greiner, L. C.; Inuki, S.; Arichi, N.; Oishi, S.; Rikito, S.; Iwai, T.; Sawamura, M.; Hashmi, A. S. K.; Ohno, H. Chem. Eur. J., 2021, 27, 12992-12997. DOI: 10.1002/chem.202101824 |
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| 207. Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant Rawat, V. K.; Higashida, K.; Sawamura, M. Synthesis, 2021, 53, 3397-3403. DOI: 10.1055/a-1509-5954 |
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| 206. A Hollow-Shaped Caged Triarylphosphine: Synthesis, Characterization and Applications to Gold(I)-Catalyzed 1,8-Enyne Cycloisomerization Iwai,T.; Goto,Y.; You, Z.; Sawamura, M. Chem. Lett., 2021, 50, 1236-1239. DOI: doi.org/10.1246/cl.210176 |
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| 205. Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids Rawat, V. K.; Higashida, K.; Sawamura, M. Adv. Synth. Cat., 2021, 363, 1631–1637. DOI: 10.1002/adsc.202001515 |
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| 204. Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms You, Z.; Higashida, K.; Iwai,T.; Sawamura, M. Angew. Chem. Int. Ed., 2021, 90, 5778–5782. DOI: 10.1002/anie.202013544 |
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| 203. Synthesis of 2-Hydroxy-2-pyridinone Derivatives and Evaluation of Their Antioxidant/Anticancer Activities Hamama, W. S.; Ghaith, E. A.; Ibrahim, M. E.; Sawamura, M.; Zoorob, H. H. ChemistrySelect, 2021, 6, 1430–1439. DOI: doi.org.10.1002/slct.202004682 |
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| 202. Dumbbell-Shaped 2,2’-Bipyridines: Controlled Metal Monochelation and Application to Ni-Catalyzed Cross-Couplings Kim, Y.; Iwai T.; Fujii,S.; Ueno, K.; Sawamura, M. Chem. Eur. J., 2021, 27, 2289–2293. DOI: 10.1002/chem.202004053 |
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| 201. Convenient Synthesis of Binary and Fused Pyrazole Ring Systems: Accredited by Molecular Modeling and Biological Evaluation Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S. ChemistrySelect. 2020, 5, 14917–14923. DOI: doi.org.10.1002/slct.202004014 |
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| 200. Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic Flow Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. Ind. Eng. Chem. Res. 2020, 59, 15179–15187. DOI: 10.1021/acs.iecr.0c02404 |
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| 199. Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M. Adv. Synth. Catal. 2020, 362, 4655–4661. DOI: 10.1002/adsc.202000615 |
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| 198. Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2020, 22, 5240–5245. DOI: 10.1021/acs.orglett.0c01905 |
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| 197. Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. ChemCatChem 2020, 12, 4034–4037. DOI: 10.1002/cctc.202000651 |
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| 196. Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M. Beilstein J. Org. Chem. 2020, 16, 537–543. DOI: 10.3762/bjoc.16.50 |
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| 195. Boron-Catalyzed α-Amination of Carboxylic Acids Morisawa, T.; Sawamura, M.; Shimizu, Y. Org. Lett. 2019, 21, 7466–7469. DOI: 10.1021/acs.orglett.9b02769 |
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| 194. Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2019, 21, 5867–5872 DOI: 10.1021/acs.orglett.9b01989 |
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| 193. Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines. Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M. J. Am. Chem. Soc. 2019, 141, 7261–7265. DOI: 10.1021/jacs.9b02751 |
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| 192. Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes Ueda, Y.; Iwai, T.; Sawamura, M Chem. Eur. J. 2019, 25, 9410–9414. DOI: 10.1002/chem.201900822. |
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| 191. Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2019, 361, 2250–2254. DOI: 10.1002/adsc.201801713 |
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| 190. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M. Org. Lett. 2019, 21, 1717–1721. DOI:10.1021/acs.orglett.9b00276 |
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| 189. A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides Arashima, J.; Iwai, T.; Sawamura, M. Chem. Asian J. 2019, 14, 411–415. DOI: 10.1002/asia.201801651 |
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| 188. P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization Iwai, T.; Shibaike, M.; Sawamura, M. Chem. Lett. 2018, 47, 1162–1164. DOI: 10.1246/cl.180501 |
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| 187. Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 9465–9469. DOI: 10.1002/anie.201802821 |
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| 186. Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand Konishi, S.; Iwai, T.; Sawamura, M. Organometallics 2018, 37, 1876–1883. DOI: 10.1021/acs.organomet.8b00113 |
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| 185. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M. Org. Lett. 2018, 20, 1861–1865. DOI: 10.1021/acs.orglett.8b00390 |
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| 184. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M. Chem. Sci. 2018, 9, 3484–3493. DOI: 10.1039/C8SC00527C |
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| 183. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M. Chem. Lett. 2018, 47, 632–635. DOI: 10.1246/cl.180147 |
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| 182. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes Yasuda, Y.; Ohmiya, H.; Sawamura, M. Synthesis 2018, 50, 2235–2246. DOI: 10.1055/s-0036-1591548 |
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| 181. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 3196–3199. DOI: 10.1002/anie.201712351 |
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| 180. Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M. Chem. Commun. 2018, 54, 1718–1721. DOI: 10.1039/C7CC08181B |
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| 179. Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M. Adv. Synth. Catal. 2018, 360, 670–675. DOI: 10.1002/adsc.201701193 |
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| 178. Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides Iwai, T.; Asano, K.; Harada, T.; Sawamura, M. Bull. Chem. Soc. Jpn. 2017, 90, 943–949. DOI: 10.1246/bcsj.20170141 |
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| 177. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand. Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M. Chem. Eur. J. 2017, 23, 8400–8404. DOI: 10.1002/chem.201702070 |
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| 176. Exploring the Full Catalytic Cycle of Rhodium(I)–BINAP-Catalysed Isomerization of Allylic Amines: A Graph Theory Approach for Path Optimisation. Yoshimura, T.; Maeda, S.; Taketsugu, T.; Sawamura, M.; Morokuma, K.; Mori, S. Chem. Sci. 2017, 8, 4475–4488. DOI: 10.1039/C7SC00401J |
| 175. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides. Hojoh, K.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2017, 139, 2184–2187. DOI: 10.1021/jacs.6b12881 |
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| 174. A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis. Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M. ACS Catal. 2017, 7, 1681–1692. DOI: 10.1021/acscatal.6b02988 |
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| 173. Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines. Iwai, T.; Tanaka, R.; Sawamura, M. Organometallics, 2016, 35, 3959-3969. DOI: 10.1021/acs.organomet.6b00752 |
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| 172. Copper-Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand. Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed., 2016, 55, 10816-10820. DOI: 10.1002/anie.201605125 |
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| 171. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett., 2016, 18, 1706-1709. DOI: 10.1021/acs.orglett.6b00677 |
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| 170. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Organometallics, 2016, 35, 1354-1357. DOI: 10.1021/acs.organomet.6b00126 |
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| 169. Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst. Murakami, R.; Iwai, T.; Sawamura, M. Synlett., 2016, 27, 1187-1192. DOI: 10.1055/s-0035-1561599 |
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| 168. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles. Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M. Angew. Chem. Int. Ed., 2016, 55, 4777-4780. DOI:10.1002/anie.201600619 |
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| 167. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Beilstein J. Org. Chem., 2015, 11, 2444–2450. DOI:10.3762/bjoc.11.265 |
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| 166. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes. Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M. ACS Catal., 2015, 5, 7254–7264. DOI: 10.1021/acscatal.5b00904 |
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| 165. Synthesis of 1,1-Diborylalkenes through a Brønsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron. Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed., 2015, 54, 15859-15862. DOI: 10.1002/anie.201509218 |
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| 164. Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes. Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M. Tetrahedron:Asymmetry, 2015, 26, 1245–1250. DOI: 10.1016/j.tetasy.2015.09.016 |
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| 163. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M. Tetrahedron, 2015, 71, 6519–6533. DOI:10.1016/j.tet.2015.05.048 |
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| 162. Copper-Catalyzed g-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes. Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M. Chem. Eur. J. 2015, 21, 9666-9670. DOI: 10.1002/chem.201501055 |
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| 161. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett. 2015, 17, 2039–2041. DOI: 10.1021/acs.orglet.5b00758 |
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| 160. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis. Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett. 2015, 17, 1304–1307. DOI: 10.1021/acs.orglett.5b00305 |
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| 159. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles. Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2014, 136, 13932–13939. DOI: 10.1021/ja508433 |
| 158. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes. Nagao, K.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2014, 136, 10605–10608. DOI: 10.1021/ja506310v |
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| 157. Stereoselective C–H Borylations of Cyclopropanes and Cyclobutanes with Silica-supported Monophosphane-Ir Catalysts. Murakami, R.; Tsunoda,K.; Iwai, T.; Sawamura, M. Chem. Eur. J. 2014, 20, 13127–13131. DOI: 10.1002/chem.201404362 |
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| 156. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper). DOI: 10.1002/anie.201402386. |
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| 155. Silica-Supported Tripod Triarylphosphane: Application to Transition Metal Catalyzed C(sp3)–H Borylations. Iwai, T.; Murakami, R.; Harada,T.; Kawamorita, S.; Sawamura, M. Adv. Synth. Catal. 2014, 356, 1563–1570. DOI: 10.1002/adsc.201301147 |
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| 154. Silica-supported Tripod Triarylphosphines: Application to Palladium Catalyzed Borylation of Chloroarenes. Iwai, T.; Harada, T.; Tanaka, R.; Sawamura, M. Chem. Lett. 2014, 43, 584–586. DOI: 10.1246/cl.131161 |
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| 153. Tripod Immobilization of Triphenylphosphane on a Silica Gel Surface to Enable Selective Mono-P-ligation to Palladium: Application to Suzuki–Miyaura Cross-Coupling with Chloroarenes. Iwai, T.; Tanaka, R.; Harada, T.; Sawamura, M. Chem. Eur. J. 2014, 20, 1057–1065. DOI: 10.1002/chem.201304081 |
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| 152. Site-selective C–H Borylation of Quinolines at the C-8 Position Catalyzed by a Silica-supported Phosphane-Iridium System. Konishi, S.; Kawamorita, S.; Iwai, T.; Steel, P. G.; Marder, T. B.; Sawamura, M. Chem. Asian J. 2014, 9, 434-438. DOI: 10.1002/asia.201301423 |
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| 151. Friedel-Crafts Functionalization of Cyclopentadienyl Ligand in Bucky Metallocenes. Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura ,E. Dalton Trans. 2014, 43, 7407–7412. DOI: 10.1039/C3DT52002A |
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| 150. Threefold Cross-Linked Polystyrene-Triphenylphosphane Hybrids: Mono-P-Ligating Behaviors and Catalytic Applications for Aryl Chloride Cross-Coupling and C(sp3)–H Borylation. Iwai, T.; Harada, T.; Hara, K.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 12322–12326. DOI: 10.1002/anie.201306769 |
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| 149. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 11620–11623. DOI: 10.1002/anie.201305973 |
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| 148. Cooperative Catalysis of Metal and O–H···O/sp3-C–H···O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes. Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H.; Mori, S.; Sawamura,M. Chem. Eur. J. 2013, 19, 13547–13553. DOI: 10.1002/chem.201301280 |
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| 147. Synthesis of a Chiral N-Heterocyclic Carbene Bearing a m-Terphenyl-Based Phosphate Moiety as an Anionic N-Substituent and Its Application to Copper-Catalyzed Enantioselective Boron Conjugate Addition. Iwai, T.; Akiyama, Y.; Sawamura, M. Tetrahedron: Asymmetry 2013, 24, 729–735. DOI: 10.1016/j.tetasy.2013.05.013 |
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| 146. Copper-Catalyzed g-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes. Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 5350–5354. DOI: 10.1002/anie.201300785 |
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| 145. Synthesis of Primary and Secondary Alkylboronates through Site-Selective C(sp3)–H Activation with Silica-Supported Monophosphine–Ir Catalysts Kawamorita, S.; Murakami, R; Iwai, T.; Sawamura, M. J. Am. Chem. Soc. 2013, 135, 2947–2950. DOI: 10.1021/ja3126239 |
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| 144. Construction of Eight-Membered Carbocycles via Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers. Iwai, T.; Okochi, H.; Ito, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 4239-4242. DOI: 10.1002/anie.201300265 |
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| 143. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters. Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M. Adv. Synth. Cat. 2013, 355, 647–652. DOI: 10.1002/adsc.201200949 |
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| 142. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes. Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 18573–18576. DOI: 10.1021/ja3093955 |
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| 141. Conjugate Reduction of a,b-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane–Copper Complex. Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 3440–3444. DOI: 10.1002/adsc.201200555 |
 |
| 140. Rh-Catalyzed Borylation of N–Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand. Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 12924–12927. DOI: 10.1021/ja305694r |
 |
| 139. Synthesis of Allenylsilanes through Copper-Catalyzed g-Selective Coupling between g-Silylated Propargylic Phosphates and Alkylboranes. Yokobori, U.; Ohmiya, H.; Sawamura, M. Organometallics 2012, 31, 7909-7913. DOI: 10.1021/om300552f |
 |
| 138. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene Complex. Yoshida, M.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 11896–11899. DOI: 10.1021/ja304481a |
 |
| 137. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 8982–8987. DOI: 10.1021/ja302520h |
 |
| 136. Practical Procedure for Copper(I)-Catalyzed Allylic Boryl Substitution with Stoichiometric Alkoxide Base. Ito, H.; Miya, T.; Sawamura, M. Tetrahedron 2012, 68, 3423-3427. DOI: 10.1016/j.tet.2011.08.081 |
|
| 135. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed g-Selective Allyl | |