ICReDD Specially Appointed Assis. Prof. Higashida
Dr. Kosuke Higashida (Original papers/Review)
Original papers
| 22.Photocatalytic 1,2-Phosphorus-Migrative [3+2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes. Masuda, Y.; Ikeshita, D.; Higashida, K.; Yoshida, M.; Ishida, N.; Murakami, M.; Sawamura, M. J. Am. Chem. Soc. 2023, 145, ASAP. (DOI:10.1021/jacs.3c06760) 21.Gold-Zinc Cooperative Catalysis for Seven-exo-dig Hydrocarboxylation of Internal Alkynes. Sato, M.; Rawat, V. K.; Higashida, K.; Sawamura, M. Chem. Eur. J. 2023, 29 in press. (DOI: 10.1002/chem.202301917) 20.Dimetal-Binding Scaffold 2-(Pyridin-2-yl)imidazo[1,5-b]pyridazine-7-ylidene: Synthesis of Trinuclear Heterobimetallic Complexes Involving Gold–Metal Interactions. Kitabayashi, A.; Ono, Y.; Taketsugu, T.; Sawamura, M.; Higashida, K. Chem. Eur. J., 2023, 29, Early View, e202301673 (Hot Paper). (DOI:10.1002/chem.202301673) 19.Visible-Light-Induced Aminochlorination of Alkenes. Mejri, E.; Higashida, K.; Kondo,Y.; Nawachi, A.; Morimoto, H.; Ohshima, T.; Sawamura, M.; Shimizu, Y. Org. Lett., 2023, 25, in press. (DOI: 10.1021/acs.orglett.3c01645) 18. Nickel-Catalyzed Defluorophosphonylation of Aryl Fluorides. You, Z.; Masuda, Y.; Iwai, T.; Higashida, K.; Sawamura, M. J. Org. Chem., 2022, 87, 14731-14737. (DOI: 10.1021/acs.joc.2c02048) 17. Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes. Rawat, V. K.; Higashida, K.; Sawamura, M. ACS Catal., 2022, 12, 8325-8330. (DOI: 10.1021/acscatal.2c01701) 16. Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of Classical and Nonclassical Hydrogen Bonds. Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.; Higashida, K.; Sawamura, M. Adv. Synth. Catal., 2022, 364, 2333-2339. (DOI: 10.1002/adsc.202200327) 15. Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols. Kitabayashi, A.; Mizushima, S.; Higashida, K.; Yasuda, Y.; Shimizu, Y.; Sawamura, M. Adv. Synth. Catal., 2022, 364, 1855-1862 (DOI: 10.1002/adsc.202200157) 14. Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y. Synlett, 2022,32, 288-292. (DOI: 10.1055/a-1673-9236) |
| 13. Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant Rawat, V. K.; Higashida, K.; Sawamura, M. Synthesis, 2021, 53, 3397-3403. (DOI: 10.1055/a-1509-5954) |
| 12. Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids Rawat, V. K.; Higashida, K.; Sawamura, M. Adv. Synth. Cat., 2021, 363, 1631–1637.(DOI: 10.1002/adsc.202001515) |
| 11. Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms You, Z.; Higashida, K.; Iwai,T.; Sawamura, M. Angew. Chem. Int. Ed., 2021, 90, 5778–5782. (DOI: 10.1002/anie.202013544) |
| 10. Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M. Adv. Synth. Catal. 2020, 362, 4655–4661. (DOI: 10.1002/adsc.202000615) |
| 9. Site-selective trans-Hydrostannation of 1,3- and 1,n-Diynes. Application to the Total Synthesis of Typhonosides E and F and a Fluorinated Cerebroside Analogue Mo, X.; Letort, A.; Roşca, D.-A.; Higashida, K.; Fürstner, A. Chem. Eur. J. 2018, 24, 9667-9674. (DOI: 10.1002/chem.201801344) |
| 8. Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and –Zinc Base Castelló-Micó, A.; Nafe, J.; Higashida, K.; Karaghiosoff, K.; Gingras, M.; Knochel, P. Org. Lett. 2017, 19, 360-363. (DOI: 10.1021/acs.orglett.6b03539) |
| 7. Iridium-catalyzed Asymmetric Hydrogenation of Tosylamido-Substituted Pyrazines for Constructing Chiral Tetrahydropyrazines with an Amidine Skelton Higashida, K.; Nagae, H.; Mashima, K. Adv. Synth. Catal. 2016, 358, 3949-3954. (DOI: 10.1002/adsc.201600852) |
| 6. Synthesis and Characterization of Heterobimetallic Tantalum–Rhodium and Tantalum–Iridium Complexes Connected by a Tantallacyclopentadiene Fragment Yamamoto, K.; Higashida, K.; Nagae, H.; Tsurugi, H.; Mashima, K. Helv. Chim. Acta. 2016, 99, 848-858. (DOI: 10.1002/hlca.201600180) |
| 5. E-Selective Semi-hydrogenation of Alkynes with Dinuclear Iridium Complexes under Atmospheric Pressure of Hydrogen Higashida, K.; Mashima, K. Chem. Lett. 2016, 45, 866-868. (DOI: 10.1246/cl.160410) |
| 4. Asymmetric Hydrogenation of 3-Amido-2-arylpyridinium Salts by Triply-chloride-bridged Dinuclear Iridium Complexes Bearing Enantiopure Diphosphine Ligands: Synthesis of Neurokinin-1 Receptor Antagonist Derivatives Iimuro, A.; Higashida, K.; Kita, Y.; Mashima, K. Adv. Synth. Catal. 2016, 358, 1929-1933. (DOI: 10.1002/adsc.201600203) |
| 3. Chloride-bridged Dinuclear Rhodium(III) Complexes Bearing Chiral Diphosphine Ligands as New Rhodium(III) Catalyst Precursors for Asymmetric Hydrogenation of Simple Olefins Kita, Y.; Hida, S.; Higashihara, K.; Jena, H. S.; Higashida, K.; Mashima, K. Angew. Chem., Int. Ed. 2016, 55, 8299-8303. (DOI: 10.1002/anie.201601748) (Inside Cover) |
| 2. Asymmetric Hydrogenation of Quinazolinium Salts Catalyzed by Halide-bridged Dinuclear Iridium Complexes Bearing Chiral Diphosphine Ligands Kita, Y.; Higashida, K.; Yamaji, K.; Iimuro, A.; Mashima, K. Chem. Commun. 2015, 51, 4380-4382. (DOI: 10.1039/C5CC00258C) |
| 1. Enhancing Effects of Salt Formation on Catalytic Activity and Enantioselectivity for Asymmetric Hydrogenation of Isoquinolinium Salts by Dinuclear Halide-Bridged Iridium Complexes Bearing Chiral Diphosphine Ligands Kita, K.; Yamaji, K.; Higashida, K.; Kandula, S.; Iimuro, A.; Mashima, K. Chem. Eur. J. 2015, 21, 1915-1927. (DOI: 10.1002/chem.201405408) (Cover Picture) |
Reviews
| 2. Triply-halide-bridged Dinuclear Iridium(III) Complexes with Chiral Diphosphine Ligands as New Easy-handling Iridium Catalysts for Asymmetric Hydrogenation of Imines and N-Heteroaromatics Mashima, K.; Higashida, K.; Iimuro, A.; Nagae, H.; Kita, Y. The Chemical Record, 2016, 16, 2585-2594. (DOI: 10.1002/tcr.201600079) |
| 1. Asymmetric Hydrogenation of Six-membered Monocyclic N-Heteroaromatic Compounds Iimuro, A.; Higashida, K.; Nagae, H.; Mashima, K. HETEROCYCLES, 2017, 95, 63-80. (DOI: 10.3987/REV-16-SR(S)1) |